School Science Lessons
(UNChemMercury1)
2025-01-23
Mercury
Please send comments to: j.elfick@uq.edu.au
Contents
See: Mercury, Table of the Elements
See: Mercury, RSC
"Heat turned on medical equipment", (World Health Organization): 3.0
Mercury (I) chloride
Mercury fulminate
Mercury (I) nitrate
Mercury (II) chloride
Mercury (II) iodide
Mercury (II) nitrate
Mercury (II) oxide
Mercury (II) sulfide
Mercury and dental amalgam: 3.3
Mercury in barometers and thermometers: 3.5
Mercury, Laboratory procedure: 3.1
Mercury metal: 3.6
Mercury properties: 3.2
"Mercury's silent toll on the world's wildlife": 3.4, (Biology)
Reactions of mercury and mercury compounds: 3.7
Sushi warning: 3.8, (Cooking)
Experiments
Biology
Body temperature: 9.3.2.1, (Clinical thermometer)
Measure osmosis: 9.12.0
Mercury toxicity: 4.1.10
Respiration of flower heads over mercury: 9.6.2
Respiration of soaked peas over mercury: 9.6.5
Root pressure: 9.3.15
Tests for proteins: 9.6.7
Transpiration by leaves exerts suction: 9.182
Physics, Astronomy, Weather
Atmospheric pressure: 13.3
Calomel half cell: 33.6.16
Capillarity, wicks: 19.3.0, (See: 4. Mercury)
Capillarity: Mercury
Thermometers: 22.7.01
Diffraction grating, spectroscope: 27.35, (See 2. mercury lamp)
Distance and diameter of planets: Table 36.25, (See: planet Mercury)
Drops and films: 19.0.1
Dry cell torch battery: 33.4.2
Electric light bulb: 4.65, (See 3. mercury lamp)
Electrical conductivity of a substance: 15.59.0
Fluid expansion: 23.32, (coefficient of volume change)
Fluorescent lamp: 38.8.3, (mercury vapour)
Force pump: 12.4.4, ( support a column of mercury)
Immersion oil: 1.14 (Mercury e line)
Lift pump: 12.4.2, (column of mercury)
Mercury barometer: 4.229
Oscillating mercury: 4.222
Pressure definitions: 12.1.01
Resistance: 32.3.02, (See 10. superconducting Hg)
Solar system model: 36.25, (Planet mercury)
Standard temperature and pressure: 20.0.6
Superconductors: 31.4.6
Thermometers and temperature: 22.7.0
torr, Pressure definitions: 12.1.01
Weston Standard Cell: 33.31
Experiments
Attraction and repulsion of parallel electric currents: 30.3.11
Barlow's wheel: 29.2.6.9
Barometer in a bell jar: 13.32
Birefringent mica: 27.188, (mercury light)
Coefficient of expansion of liquid in flask and U-tube: 23.2.9
Crookes' radiometer: 20.4.2
Dancing spring: 30.3.10
Density of liquids with U-tube: 11.1.1
Electromagnetic conical pendulum: 29.2.6.12
Float an iron ball in mercury: 4.212
Interacting solenoids: 29.2.7.4
Maxwell's rule: 29.2.6.8
Mercury barometer: 4.229
Mercury shaker: 31.1.21
Oscillating mercury, "chemical battery": 4.222
Parallel conductors: 29.2.6.1
Pinching mercury: 29.2.5.7
Pressure affects the boiling point: 2.8
Reaction time of equipment: 3.3.3.2, (mercury thermometer)
Simple barometer: 13.31
Thermometer test: 22.7.3
Chemistry, Geology, Safety
Mercury: 35.20.26, (Geology)
Activity series of metals as reducing agents: 12.14.0
Calomel: 35.20.10.1
Chemical spill kit: 3.82
Chemicals not permitted in schools: 15.10.0
Chlorine dioxide: 13.4.5
Cinnabar: 35.20.10.0, (Geology)
Daguerreotypes: 12.19.4.1
Group analysis: 17.5.7.0
Group 1 tests: 12.11.4.1
Mercury (II) acetate, C4H6O4Hg, Hg(OAc)2
Mercury (II) cyanide, gold mining contaminant
Mercury meta: 7.0.2 See: 6.
Mercury residues: 3.5.4, (disposal)
Mercury toxicity: 4.6.10
Methyl mercury, CH3Hg +
Millon's reagent: 9.6.7
Nessler's reagent
Odour and taste: 35.15
Old Nassau flag clock reaction: 17.1.7, (mercury (II) iodide)
Organomercury: methyl mercury CH3Hg + , ethyl mercury C2H5Hg + , dimethyl mercury (CH3)2Hg, merbromin C20H8Br2HgNa2O6
Poisons and First Aid: 3.10.0, (Millons's reagent, Mercury and mercury compounds, mercuric chloride)
Primary ore deposits: 35.3.01
Reactions of mercury compounds: 3.7
Separate metals by reduction of metal oxides: 10.10.0, (Not mercury)
Sodium amalgam
Sushi warning: 3.8, (Cooking)
Tests for proteins: 9.6.7
Toxicity, Poisons and First Aid: 3.10.0
Toxicity: 3.6.01
Waste bottles: 7.9.55.1
Zenker's fluid: 4.6
3.0 "Heat turned on medical equipment", (World Health Organization)
Courier Mail (Brisbane) October 12, 2013
The World Health Organization and anti-mercury campaigners have launched a drive to wipe out the heavy metal in medical thermometers.
The move came a day after representatives of 140 nations signed an UN treaty to control the use of mercury.
"Mercury is one of the top l0 chemicals of major public health concern and is a substance that disperses into and remains in ecosystems for generations, causing severe ill health and intellectual impairment
to exposed populations, " WHO director-general Margaret Chan said.
Working with the campaign group Health Care Without Harm, the UN agency said it aimed by 2020 to eliminate mercury from fever thermometers, and blood pressure devices that use it.
The goal would be achieved if the manufacture, import and export of such devices were halted and accurate, affordable, and safer non-mercury alternatives were deployed.
In Japan, delegates from more than 140 countries and territories signed an UN treaty on mercury, in the city of Minamata.
The location was highly symbolic, as Minamata was the scene of a mercury scandal exposed in the 195Os.
3.1 Mercury, Laboratory procedure
Mercury can evaporate even at 0 o C.
Mercury vapour absorbed by the body is not detoxified by the body and may accumulate and cause complications with the nervous system.
When mercury contacts with your skin you must thoroughly wash the area with soap and water immediately.
Mercury should be stored in an impervious container made of glass or china in a cool ventilated place.
While storing mercury under water is useful, it is not sufficient.
Mercury should be stored in a sealed container.
The container should be placed in a sealed cupboard or a sealed larger container or box.
There should be some powdered sulfur or powdered zinc alongside the mercury container to be used in case of emergency with a mercury spill.
The table used for a mercury experiment should be smooth and no slits.
If there are some slits on the table make them smooth and cover it with paint.
Use mercury in a well-ventilated area that does not have porous surfaces.
Do not heat mercury, because more toxic mercury vapour is given off.
Liquid mercury boils violently at atmospheric pressure.
Do not react mercury with chlorine or bromine, because highly toxic salts are formed.
Mercury reacts with the gold in gold rings to form an amalgam and spoil the ring.
Spillage and cleanup
Mercury metal gives off a highly toxic vapour that acts as a cumulative poison.
Spilt mercury shatters into many tiny droplets that lodge in cracks in the floor and around skirting boards.
The droplets have a large total surface area and the mercury can evaporate slowly, causing long-term exposure to low levels of mercury vapour in the air.
Any person working in the area may regularly inhale the mercury vapour, with adverse effects.
Spilt mercury must be immediately treated with sulfur powder or mercury decontaminant, a mixture of calcium hydroxide and sulfur, to form low vapour pressure mercury (II) sulfide that is stable and harmless and can be easily cleaned up from the polluted region.
Then sweep up the mercury and sulfur together.
If mercury is found to be leaking or spilt in a room, the persons in the room must go out of the room, and open all the system of ventilation and shut the doors next to that room.
Mercury that has leaked out should be absorbed by water pump or cleaned by wet cleaning agent.
Put the collected mercury into a glass bottle.
The person who cleans the mercury up should check that all the mercury has been cleaned up, and that none remains on the cleaning cloth.
Always keep available 2 kg of sulfur or 2 kg of mercury decontaminant in the laboratory, near any equipment containing mercury.
Liquid mercury is extremely dense, so the weight of even a small container may surprise some students who may then drop it.
If the pressure measured with a mercury-in-glass manometer, suddenly changes, because of the careless opening of a tap, the moving column of mercury may break the walls of the manometer and mercury spills out.
Do not place mercury thermometers in a dish washer for cleaning.
Drains in laboratories often contain significant amounts of mercury in the S-bends.
Periodically check the waste water filter of a laboratory dishwasher for liquid mercury.
Store mercury in a sealed container on a plastic tray to catch any spilt mercury.
Before disposal of broken thermometer debris or mercury-contaminated rubbish from S-bends, mix them with an equal volume of sulfur powder.
Fit a tray containing a centimetre of sulfur powder beneath the apparatus, because mercury spilled on sulfur powder will not shatter into fine droplets and the sulfur will inactivate the mercury.
Pour mercury over a plastic tray containing water so that any spilled mercury will not shatter into droplets, but form a lower layer that can be recovered easily.
Uses for dentistry amalgams, mercury cathode in mercury cell, mercury solvent of metals to form amalgams, mercury vapour lamps, electrical switches, interferometer lights, batteries, thermometers, barometers, thermostats and detonators, e.g. mercury fulminate.
Mercury is used in its pure form in thermometers and barometers and as a catalyst in the chemical industry.
It is also used in the mining industry to extract gold and silver ores.
Fluorescent lamps containing mercury vapour or neon gas are much more energy-efficient than incandescent lamps.
3.2 Mercury properties
Warning!
Mercury is not permitted in schools except in some school systems where it is allowed only in barometers and thermometers.
Junior students should use alcohol or electronic thermometers.
Avoid the use of mercury by using solid state electronic devices for measuring pressure or use less dense liquids, even water, in a manometer, to demonstrate changes in pressure.
Mercury, Hg, (Latin Mercurius Roman god), Mercury (RD 13.60), (Latin hydrargyrum, formerly "quicksilver", Hg) is a liquid metal between 19 o C and 27 oC, it has the lowest melting point of all substances, mp = -38.9 o C, it is slightly volatile at ordinary temperatures.
Atomic number: 80, Relative atomic mass: 200.59, RD
13.6, mp: -38.9 o C, bp: 357 o C, Specific heat capacity: 138 J kg -1 K -1 , type 1 superconductor at 4.2 K, melting point 234.28 K
Density 13.60 g cm -3 , Specific Gravity: 13.6 Vapour Pressure: 0.0012 (mm Hg / 21 o C)
Anomalies in the properties of an element, e.g. mercury, Hg, is liquid at room temperature.
One mole of a non-electrolyte dissolved in water and made up to 22.4 L of solution causes an osmotic pressure, at 0 oC of 760 mm of mercury (1 atmosphere).
3.3 Mercury and dental amalgam
Statement approved by the 107th session of the National Health and Medical Research Council, Sydney, Australia.
"An amalgam is a metal alloy where one component is mercury.
Dental amalgam is prepared by mixing silver-tin powder with liquid mercury.
The resulting mix then hardens to form a stable solid as mercury forms compounds with the silver and tin.
Dental amalgam is an excellent material for repairing decayed teeth, and for many applications it is still preferable to the alternatives.
Amalgam is stronger, and therefore lasts longer than the composite resins (plastics) or synthetic cements.
Amalgam is chemically much less damaging to the local tissues than these materials, and it keeps bacteria out extremely well.
As some forms of mercury are toxic, the safety of dental amalgam for dental patients, and for dental care workers, has been thoroughly examined.
The vapour of pure mercury does pose a health hazard if it is inhaled either in very high concentrations for a short time or in moderate concentration for months or years.
Mercury vapour crosses the lungs into the blood quite readily, and then moves from the blood into other tissues.
This is a possible risk to dental health workers if mercury hygiene is not practised and their workplace becomes contaminated, but it is not a risk to patients receiving amalgam fillings, because their exposure
to vapour is extremely low.
Also, the occasional inorganic mercury compounds, such as those formed when dental amalgam is mixed, are poorly absorbed and are readily excreted by the kidneys.
Mercury compounds are present in many foods in low concentrations and cause no harm.
The health and well being of dental patients who have received amalgam fillings has been studied thoroughly, and the following findings were arrived at:
1. There is no difference in the incidence of any disease or in the length of life between people who have amalgam fillings and those who do not.
2. People who have amalgam fillings and then have them removed do not experience an improvement in health.
3. People who have no teeth, and therefore no amalgam fillings, are not healthier than people with amalgam-filled teeth.
4. Rarely, allergy to amalgam occurs as a local rash on the cheek or tongue next to a filling.
For patients with such allergy, material other than amalgam should be used.
Dentists and dental researchers are interested in finding ways to repair teeth without using dental amalgam, because of the industrial risks that amalgam poses to dental care personnel.
Patients sometimes request fillings made with materials other than amalgam, because of the concerns about safety and appearance.
Some alternative materials can be used, but they are often less satisfactory than amalgam from the point of the patient's long term health and well being.
Dental amalgam is still the material of choice for the repair for most medium sized areas of tooth decay in premolar and molar teeth.
The objective of the National Health and Medical Research Council is to advise the Australian community on the achievement and maintenance of the highest practicable standards of the individual
and public health and to foster research in the interest of improving those standards."
[Editorial comment: The research is not very clear and confusing.
Properly and accurately mixed amalgams are probably sufficiently stable to not cause any problems over a lifetime.
Inaccurately mixed amalgams may leak (leach) enough mercury to cause some minor effects after a long time in a small number of genetically pre-disposed individuals.
Another issue for the dental professions was what else to use?
It has only been in the past few years that useful alternatives have been available.
About half the current dentists use the alternatives.
Previously, students studied the interesting chemistry of mercury salts.
To my knowledge, there has not been one health problem related to mercury in these thousands of students.]
3.4 Mercury's silent toll on the world's wildlife
Coal burning, gold mining, and other human activities release mercury into water bodies or the atmosphere, where it can travel great distances before settling back to Earth.
Mercury from coal burning can travel great distances, for instance, from China to North America - before settling.
Exposed animals have trouble ridding their bodies of mercury, and it accumulates in tissue with every link in the food chain.
Long-lived predators tend to carry the heaviest loads.
Research and public attention have largely focussed on contaminated fish, the main route of human exposure.
In water, mercury converts quickly to methyl mercury, its most toxic form, so for many years wildlife biologists trained their sights on aquatic, fish-eating birds and mammals.
Others have uncovered mercury in reptiles, amphibians, insects, spiders, terrestrial songbirds, and a wider variety of mammals than expected.
Scientists have found mercury-laden food chains in mountainous forests, and shown that methyl mercury forms in the woods, as well as in water.
Mercury plays havoc on vertebrates' development and their neurological and hormonal systems, and doses too low to kill can cause problems that are not always obvious in the wild.
Much of the research on mercury's sub lethal effects has been conducted on captive animals.
In nature, it's very difficult to get the large sample sizes and control groups needed to identify subtle differences statistically.
Methyl mercury, [CH3Hg]+ is the simplest organomercury compound and is extremely toxic, possibly one of most toxic environmental pollutants.
Methyl mercury is a hazardous substance, as inorganic mercury circulating in the general environment is dissolved into freshwater and seawater, condensed through the food chain, ingested by humans, and consequently affects human health..
In humans, blood levels around 0.005 ppm can cause cognitive deficits.
Toads readily move between small populations scattered throughout the landscape.
Mercury exposure can kill eggs and tadpoles, and survivors are often small and slow to mature.
3.5 Mercury in barometers and thermometers
1. Thermometers supplied to schools usually contain alcohol and not mercury.
Avoid leaving thermometers in containers where they are easily knocked over by students.
To monitor the temperature continuously, clamp the thermometer in position.
If recording the temperature at regular intervals, return the thermometer to its container between measurements.
Do not leave thermometers on the desk where they may be moved by the elbows or the back of the hand.
Do not place laboratory thermometers in the mouths of students.
Do not use thermometers to stir liquids, because the liquid in the thermometer may separate, making it unusable.
However, you can put the thermometer in a refrigerator freezer until the liquid recombines.
Do not try to recombine the liquid by heating the thermometer, because it may explode.
Primary and junior secondary classes should use alcohol thermometers, not mercury thermometers, and they may observe a mercury barometer attached to the wall, if supplied by the education authority.
2. Do not use mercury in school experiments.
However, students may observe some properties of mercury by studying it as enclosed in a barometer or thermometer supplied by the education authority.
Do not make a barometer or a thermometer using mercury.
Mercury vapour is TOXIC and may damage the nervous system.
Mercury enters the body readily by inhalation by ingestion or through the skin.
If mercury is spilt from a broken thermometer, immediately pick up all the mercury with pieces of stiff cardboard, e.g. a bent playing card, or with a damp cloth or a water suction pump.
Do not use a vacuum cleaner or a broom.
Do not put spilt mercury down the drain.
Sprinkle sulfur powder or zinc powder over the area of the spillage and collect it with a moist absorbent paper.
Shine a light on the spillage to see the mercury globules.
Report any mercury spill to the school authorities.
Give any spilt mercury or mercury stored in the school laboratory to a government laboratory.
4. The World health Organization, working with the UN agency Health Care Without Harm, has launched a campaign to eliminate mercury from fever thermometers and blood pressure devices by 2020.
3.6 Mercury metal
Mercury is a heavy metal that is widespread and persistent in the environment.
It is a naturally occurring element and can be released into the air and water through weathering of rock containing mercury ore, or through human activities such as industrial processes, mining, deforestation,
waste incineration, and burning of fossil fuels.
Mercury can also be released from a number of mercury-containing products, including dental amalgam, electrical applications (e.g. switches and fluorescent lamps), laboratory and medical instruments, (e.g. clinical thermometers and barometers), batteries, seed dressings, antiseptic and antibacterial creams, and skin-lightening creams.
Mercury exposure can affect foetal neurological development and has been linked to lowered fertility, brain and nerve damage, and heart disease in adults who have high levels of mercury in their blood.
Since 2001, the UN Environment Programme Governing Council/Global Ministerial Environment Forum, (UNEP GC/GMEF), regularly discussed the need to protect human health and the environment from
the releases of mercury and its compounds.
The sixth session of the Intergovernmental Negotiating Committee to Prepare a Global Legally Binding Instrument on Mercury, (INC6), convened from 3-7 November 2014, in Bangkok, Thailand. INC6 carried out work to prepare for the entry into force of the Minamata Convention on Mercury and for the first meeting of the Conference of Parties, (COP1).
Over 300 participants attended the session, representing 122 governments, as well as 29 non-governmental and 13 intergovernmental organizations.
Following a round of regional group meetings on Sunday, 2 November, delegates began their work.
Issues under consideration included, inter alia: importing mercury, registering exemptions, reporting and monitoring, rules of procedure and financial rules for the COP, guidance and assistance to countries with artisanal and small-scale gold mining, storage, wastes and management of contaminated sites, and operation of the financial mechanism.
3.7 Reactions of mercuryand mercury compounds
Mercury metal and mercury compounds are not used in school science experiments.
Mercury forms mercury (I) and mercury (II) salts.
Mercury is very low in the electrochemical series and so nearly all metals precipitate it from solution.
Mercury hydroxide, carbonate and oxide are unstable and produce mercury when heated.
Mercury (I) salts in solution form the unusual ion Hg2 2+ .
However, mercury (II) salts ionize only slightly.
Mercury, a naturally occurring element that rarely occurs free in rock cavities, is an odourless, very heavy, silver white, liquid metal.
Pure mercury is stable and does not tarnish at ordinary temperatures.
It will form alloys with most metals.
It is not soluble in water or most other liquids, but will dissolve in lipids (fats and oils).
It is an excellent conductor of electricity.
Mercury dissolves in most metals to produce amalgams.
Mercury dissolves gold and if a gold leaf is placed on top of a globule of mrecury, the mercury appear to pull the whole gold leaf into the globule.
dissolves other metals to from an amalgam.
add gold leaf gets pulled in.
It reacts with concentrated oxidizing acids, HNO3 or H2SO4 to produce high oxidation number ions, and sulfur dioxide SO2 or nitrogen dioxide, NO2.
No reaction with dilute HCl or H2SO4 or with water.
Heated powder forms oxide.
It is extracted from cinnabar (mercury (II) sulfide).
Sodium amalgam, NaHg2, is formed by electrolysis of sodium chloride solution with a mercury cathode.
Mercury and mercury salts react with aluminium in a violently exothermic reaction.
3.8 Merbromin
Merbromin, C20H8Br2HgNa2O6, Mercury dibromofluorescein disodium salt, is an organic sodium salt , 2,7-dibromo-4-hydroxymercurifluorescein.
Merbromin + dark red fluorescein, 2% solution = Mercurochrome, " monkey blood", household topical antiseptic.
When suspended in water or alcohol, it stains the skin red to brown.
It is used as an antiseptic drug, a fluorochrome and a histological dye.
"Mercurochrome", TN merbromin was commonly used as a topical first-aid antiseptic.
It is not sold in Switzerland, France, Germany, and the United States, probably because it contains mercury, despite no evidence it is not safe for topical use.
3.9 Warning on sushi
Bigger fish eat smaller fish, so the larger the fish, the greater the possible concentration of methyl mercury.
Researchers from Rutgers University, near new York, found that eating a lot of sushi increases the risk of exposure to dangerous levels of mercury.
The researchers say the fish contains methyl mercury which can cause heart disease, problems with brain and nervous system development and decreased cognitive performance.
Large tuna, e.g. Atlantic blue fin, had the highest level of methyl mercury, but also eel, crab, salmon and kelp contain it.
Mercury (I) chloride, Hg2Cl2
Calomel, horn quicksilver, Hg2Cl2: 35.20.10.1 (Mineral)
Calomel half cell, Hg2Cl2 : 15.6.16
Calomel, Standard electrode potential, E 0 : 3.84.6
Mercury (I) chloride, Hg2Cl2, calomel, mercurous chloride horn quicksilver, white crystals, RD 7.15, sublimes at 400 o C, (reference
electrode in calomel electric cells, mercury electrode in potassium chloride solution + calomel).
Calomel is found with cinnabar mineral, is a former laxative, and has low toxicity.
Formerly, calomel was a tasteless, grey, usually powdered, medicine used as a purgative.
Calomel is found with cinnabar mineral.
Formerly used as a laxative.
Solution / mixture < 25%, Not hazardous
Mercury (I) nitrate
Mercury (I) nitrate dihydrate, Hg2(NO3)2.2H2O, (Millon's reagent)
Tests for proteins, Millon's test: 9.6.7
Millon's reagent contains mercury (I) nitrate, mercurous nitrate, in nitrous acid.
Mercury (I) nitrate dihydrate, Hg2(NO3)2.2H2O, mercurous nitrate dihydrate, forms explosive mixtures with combustible materials and organic compounds.
Mercury (I) nitrate was formerly used in the manufacture of felt hats, and caused tremors in the workers and leading to the term "mad as a hatter".
The "mad hatter" is a character in "Alice in Wonderland" by Lewis Carroll.
Low Toxicity if pure chemical ingested, explosive mixture with combustibles or organic compounds
Solution < 0.1%, Not hazardous but use < 5 mL of 0.1 M per activity.
The pure chemical has low toxicity if ingested.
Mercury (I) nitrate is used in redox reactions and metal displacement reactions.
Mercury (II) chloride, HgCl2
Mercury (II) chloride, HgCl2, mercuric chloride, mercury bichloride, mercury sublimate, corrosive sublimate, mercury perchloride
Colourless, white crystalline solid, odourless, rhombic crystals, powder or granules, RD 5.4, MP 277 o C, solution is poisonous and very dangerous, because the solution looks like water.
Mercury (II) chloride should NOT be in the school laboratory!
It was formerly used to treat syphilis.
Used for manufacture of disinfectants, catalyst. photography, embalming.
Bacteria in the water and the soil primarily produce methyl mercury.
Mercuric chloride is soluble in water and in most organic solvents, but methyl mercury is not soluble.
Contact with mercuric chloride can cause burns to the skin and permanent damage to the eyes.
Methyl mercury builds up in the tissues of fish and shellfish.
Photographic toners contain mercuric chloride.
Mercuric chloride is slightly volatile at ordinary temperatures.
Melting Point: 277 o C Boiling Point: 320 o C Specific Gravity: 5.4 Vapour Pressure: 1.3 (mm Hg /21 o C)
Mercury (II) chloride, HgCl2, Highly toxic if ingested or absorbed through skin
Mercury (II) chloride, vermilion, China red, opaque red pigment, from cinnabar mineral
Mercury (II) chloride, Solution < 0.1% Not hazardous but should not be ingested.
Corrosive sublimate, HgCl2, mercury (II) chloride, mercuric chloride, Highly toxic if ingested or absorbed through skin 16.6.7
Zenker's fluid, biology fixative, (mercuric chloride): 4.6
16.6.7
Mercury (II) fulminate, Hg(CNO)2.H2O
Mercury (II) fulminate, mercury fulminate Hg(ONC)2, contact explosive, in detonators and percussion caps
Mercury (II) iodide, HgI2
Mercury (II) iodide, mercuric iodide, mercury iodide
Highly toxic if ingested or absorbed through skin
Solution < 0.1%, Not hazardous, but should not be ingested.
Nessler's reagent / solution (K2HgI4, HgI2 in KI), tests for ammonium radical, NH4 + : 11.3.10.2
Old Nassau flag clock reaction, (orange and black) sodium metabisulfite, Mercury (II) iodide: 17.1.7
Mercury (II) nitrate, Hg(NO3)2
Mercury (II) nitrate monohydrate, Hg(NO3)2.H2O, mercuric nitrate monohydrate.
Highly toxic if ingested, cumulative poison, Highly toxic if ingested or absorbed through the skin, cumulative poison.
Use eye and skin protection when splashes can occur.
Forms explosive mixtures with combustible materials and organic compounds.
Do NOT heat the solid, because mercury vapour and nitrogen dioxide forms.
Do NOT add ethanol to solutions of mercury (II) nitrate in nitric acid, because highly explosive mercury fulminate forms.
Do NOT use for redox reactions.
Use < 5 mL of 0.1 M per activity.
Mercury (II) oxide HgO
Mercuric oxide battery: 3.9
Mercury (II) oxide, HgO, red mercuric oxide,
Highly toxic if ingested, cumulative poison
Mercury (II) oxide, Solid mixture < 0.1%, Not hazardous
Mercury (II) oxide, HgO, mercuric oxide, "red calyx of mercury", yellow to orange, dense, odourless powder, RD 11.14, decomposed by light, yellow oxide of mercury or red oxide
of mercury, store in dark bottles.
Do not heat to form oxygen gas, because highly toxic mercury vapour forms.
Mixture with powdered sulfur is explosive.
Do NOT heat mercury (II) oxide to form oxygen gas, because highly toxic mercury vapour forms.
Mixture with powdered sulfur is explosive.
Mercury (II) sulfide, HgS
Mercury (II) sulfide, HgS, cinnabar, metacinnabar, mercury (II) sulfide red: 35.20.10.0
Mercury (II) sulfide pigment, (vermilion, cadmium vermilion red, red 106, Chinese red), highly toxic, cumulative poison
Methyl mercury, CH3Hg +
Methyl mercury is soluble in most organic solvents.
Mercury released into the environment is converted into methyl mercury by bacteria.
The methyl mercury will then build up in the tissues of fish and shellfish.
Humans (and other animals) may also be poisoned by eating these fish or shellfish.